Despite progress over the past twenty years in understanding of the physics and chemistry that govern air quality, there are a number of unsolved issues in this field. A lack of extensive and continuous observations is partly to blame for this situation. Although there are routine observations of air quality in some areas, such observations typically are made at ground level and cover a limited set of species. Thus, atmospheric chemists have relied on intensive measurement campaigns to address the most pressing questions.
The main goal of the Etude et Simulation de la QUalite de l'air en Ile-de-France (ESQUIF) project was to characterize pollution in a large urban area and test the ability for air quality models to reproduce the most important features of the urban plume. The campaign involved extensive measurements in the Paris (France) region (Figure 1), a site selected for several reasons to allow the major focus to be on chemical issues. First, Paris is distant from the ocean or mountains, such that the effects of variable orography are minor and meteorological parameters should be straightforward to simulate. Second, it is one of the greatest urbanized area in Europe, and it is located far from other big cities, so that the signatures and origins of pollution are easier to determine.

During ESQUIF, measurements were performed mainly during the summers 1998 and 1999 in a dozen 1-3 data intensive observation periods (IOPs). The instrumental set-up was extensively described in [Menut et al.., 2000] and [Vautard et al., 2001]. The goal of this overview is to highlight the main results obtained during the project. Additional detail can be found in subsequent articles of this special section, most of which focus on subsets of results obtained during individual IOPs. We present here an overview of these IOPs. Because results discussed in the following papers deal mostly with photochemistry (i.e. chemical regimes, sensitivity to emissions, etc.), and not Meteorology, here we will present an overview of the main meteorological situations during the campaign.
Prior to the field campaign, the ESQUIF scientific committee raised a number of key scientific points that would be addressed by the campaign and during subsequent numerical experiments. The main issues that were addressed in detail are:
Paris typically is not a very polluted city. This is due mostly to dilution of the urban plume by relatively clean oceanic air and significant dispersion by prevailing winds. In order to analyze clear signals from urban pollution we had to focus on the specific, but rare occasions when prevailing winds were very weak. Thus, a successful IOP required the availability of accurate weather and chemical forecasts several days in advance.
Weather forecasts with a specific attention on this campaign were provided by Meteo-France. Chemical forecasts were performed using several approaches. At the beginning of the campaign (e.g., 1998-1999), operational forecasts of ozone and NO2 were only available from statistical models operated by the regional air quality monitoring network AIRPARIF. At that time, several chemistry-transport models (CTMs) had also been developed, but they were not fully validated. Thus, ESQUIF provided a unique opportunity to test and validate CTMs in forecast modes. In fact, only the CHIMERE model was ready to do such a forecast exercise at that time, and those results are reported in [Vautard et al., 2001].
| IOP | Dates | Airmass origin | Remarks (whole IOP) |
| 1998 summer | |||
| 1 | 25 -> 26/07/1998 | Continental. 1-2 days stagnation | Mostly cloudy by medium and high clouds. no wind |
| 2 | 06 -> 12/08/1998 | Continental. 2-4 days stagnation | Clear sky. Hot temperature. Light winds |
| 1999 summer | |||
| 3 | 16 -> 17/06/1999 | Continental 3-4 days stagnation | Overcast after 12UT. Wind (NE) < 3 m/s |
| 4 | 25 -> 26/06/1999 | Continental. 3-4 days stagnation | Clear sky. Wind (E) ~ 5 m/s |
| 5 | 01 -> 02/07/1999 | Maritime | Clear sky. Wind (SE) ~ 4 m/s |
| 6 | 16 -> 18/07/1999 | Maritime then stagnant | Clear sky |
| 7 | 24 -> 25/07/1999 | Continental. 2-3 days stagnation | Paris plume tracking in Brittany. Windy |
| 8 | 28 -> 31/07/1999 | Continental. 3-4 days stagnation | Light wind < 2 m/s |
| 1999-2000 winter | |||
| 9 | 07 -> 08/10/1999 | Continental. 2-3 days stagnation | Anticyclonic situation. NO-> NO2 experiment |
| 10 | 26 -> 28/01/2000 | Continental | High [NOx]. Plume to West of Paris |
| 2000 summer | |||
| 11 | 19 -> 20/07/2000 | No photooxydant peak, moderate wind | Aerosols experiments |
| 12 | 30 -> 31/07/2000 | Dry conditions, no stagnation | Aerosols experiments |
To highlight IOPs periods from the summers of 1998 and 1999, the main meteorological characteristics of these summers are presented. To appreciate their differences, characteristics of the various IOPs are compared in Section 2. Finally, the research topics studied during the project are described. The major new findings are outlined, with emphasis on those that are described in more detail in the papers that follow.
Figure 2 presents a synthesis of dynamical and chemical conditions that occurred during the summers of 1998 [left panel] and 1999 [right panel]. Within each plot, intensive observation periods (IOPs) are shaded gray. For wind speed |U| (m/s, surface temperature (oC) and cloudiness (0-1), data are issued from ECMWF fields (at the first vertical level i.e z ~ 35m) and diurnally averaged over a day. The bottom panel corresponds to AIRPARIF network [O3] (ug/m3) surface measurements: for each day, the value displayed corresponds to the [O3] peak over the whole Paris area. Figure 2 indicates that the mean wind speed varied from 0 to 8 m/s. However, IOPs were always scheduled for relatively stagnant periods when wind speeds were less than 2m/s (except for IOP4, where winds were 3m/s). In 1998 and 1999, all IOPs occurred when temperatures were highest. For example, during IOP2 the highest temperatures during the entire summer of 1998 were observed. In addition, cloudiness (integrated over the whole atmospheric column) was highly variable. During IOPs, averaged cloudiness was always less than 0.4 (with a maximum of 1). Finally, IOPs occurred when highest [O3] concentrations prevailed, consistent with the situation for temperature.
For the entire set of summertime IOPs, some meteorological values were similar, but different phenomena were also observed. Although the result was always an observed peak in oxidant levels, the meteorological situations were not identical. The differences were mainly due to differences in the synoptic origins of the air masses. A large portion of France lies along the coast of the Atlantic Ocean (west), whereas another part is surrounded by very industrialized countries (north and east). Thus, relatively clean or relatively polluted air masses are advected over Paris, depending on the direction of the prevailing winds.
For most of the IOPs, peaks in pollutants were observed when air masses remained for several days over large sources regions, such as Benelux and Germany at the north and north-east of the Paris area (IOPs 1, 2, 3, 7, 8). But there were also occasions when high levels of pollutants were observed in conditions where air masses originated from the Atlantic Sea (IOPs 2, 5 and 6) (e.g. relative clean maritime air). A common feature of these latter situations was the very weak winds. Consequently, even though air masses originated from over the sea during these IOPs, stagnant conditions occurred over Paris, accompanied by high temperatures and clear skies.
Based on results from the IOPs, pollutants observed during the ESQUIF project can be split into two components, from air masses advected over the region and from local sources. Such a characterization of sources is a well-known problem in defining the chemical boundary conditions for initialization of models(see Section 4.1). Thus, another goal of the ESQUIF project was to quantify the transport of pollution from Paris to other regions. In the area surrounding Paris, such pollution consists of transport of 'ozone plumes' originating in Paris. The impact of such plumes was quantified in terms of chemical regimes during IOPs 6 and 8, results of which are presented in [Sillman et al, 2003]. At still larger spatial scales, long-range transport of pollution several hundred kilometers from the city (IOPs 4 and 7) is important. During ESQUIF, 2003 was studied using the technique of adjoint modelling sensitivity [described in Schmidt and Martin, 2003].
Not only were there differences between IOPs, meteorological and chemical variations were observed within an individual IOP. For example, during the IOP2, when the first day was characterized mainly by local production of oxidants, the end of the period was characterized by mixing of local sources with those transported from long range (see also [Menut et al., 2000b]). Whereas the beginning of the IOP (7 August 1998) brings mainly oceanic air masses (from the Atlantic Ocean) with low concentrations of pollutants, a change of the wind direction occurred during the IOP, and winds show, such that the air masses stagnate over strong source areas (Great Britain, the Benelux countries and the Rühr area in Germany). The observed local changes are, of course, influenced by synoptic changes. The impact of this is seen, in particular, in the vertical temperature soundings. From 7 to 9 August 1998, the height of the temperature inversion increases from 800m (at the maximum) to 2800m [Hourdin et al., 2001]. These changes considerably influence the capacity of the boundary layer to vertically mix the primary pollutants emitted within the surface layer, as well as the ability to exchange polluted air with relatively cleaner air from more distant regions at higher altitudes. A study, based on lidars profiles performed in Palaiseau (25km southwest of Paris), characterizes the coupling between the residual layer and the convective layer at the beginning of the day [Fochesatto et al., 2001]. By comparison with simulations performed with the meso-scale MESO-NH model [Lafore et al., 1998], it was shown that the residual layer could strongly interact and exchange with the convective layer and, thus, was not entirely isolated.
A synthesis of the average and maxima of surface ozone concentrations (in ug/m3) observed in Paris and in the entire Paris area are shown in Table 2. The hours corresponding to these peaks are also reported. For the "regional" peaks, also reported are the position of the station relative to Paris (for example, W = station in the West of Paris). Concentrations exceeding the 'public alert' threshold of 180 ug/m3 are shown in bold in Table 2.
The concentrations of ozone within Paris are always less than those over the whole region. This is explained by titration of ozone by NO, which is most strongly emitted within the city. For the few days when this is not the case, it is noted that the "regional" peak is, in fact, observed for a peri-urban station, very near the city. This feature highlights the problem of representativity of ground sampling. The characterization of the representativeness of surface stations for analysis and data assimilation is of primary interest, and constituted one of the main research thrusts of this project [N. Blond, 2002].
Within the city of Paris, peaks in ozone were observed 1 to 3 hours before the maxima over the entire region were observed. This is explained by the transport of the ozone plume. Under weak wind conditions, the plume remains within the region of the city, and its concentration continues to increase as it travels over the strong peri-urban sources. The majority of the peaks occur in mid-afternoon, during maximum solar insolation. They occur during hours that vary widely between 11:00 and 16:00 UTC. This range is the result of small-scale meteorological processes that are poorly sampled and, thus, badly simulated. In particular, the peaks are determined by the urban ABL growth rate and maximum depth, and the role of the entrainment zone, as well as the role of thin residual layers where ozone is trapped. One notable exception to this is the peak that formed on 12 August 1998 (IOP2). In this particular case, a major pollution episode is ending, and the strong nocturnal concentrations observed correspond to ozone produced during the previous the day (August 11, the most polluted day of summer 1998).
The ESQUIF experiment was designed to provide a more complete description of the atmospheric chemical composition up and around the Paris city. This goal was achieved by the use of numerous aircraft measurements at several ranges from the city center and different altitudes. The field studies were devoted, in part, to examine of the chemical boundaries of the studied domain. This was the first step in characterization of the relative magnitudes of advected air masses on local pollutants. In the region surrounding Paris, studies were carried out to evaluate the impact of photolysis on chemical reaction rates. Within the Paris area, comparisons were done between the large set of measurements and model simulations constrained by local emissions data [Vautard et al., 2003].
Another part of the field research component was devoted to the small-scale processes occurring within the studied domain. This concerns mainly the vertical exchanges of pollutants within the boundary layer, the stability of the residual layer [Fochessatto et al., 2001], and a new non-local mixing parameterization in the dynamical model LMDz [Hourdin et al., 2002].
With no important orographical forcings, over the Paris area one can expect a fairly simple meteorology that is relatively easy to simulate. But in the absence of dominant forcing, it is also necessary to better understand meteorology at longer distances. Even if the main goal of the project remains the Paris area (~100x100km), from the very start of the project it appeared that it was necessary to carry out measurements over the whole of northern France (~800x800km). This justified the choices of aircraft measurements at the mesoscale to understand origins of the air masses entering Paris. In the same way, this explains the IOP7 measurements strategy, in order to follow the Paris ozone plume towards the West of France.
The experimental results highlight the limitations of CTMs that employ "climatological" boundary conditions. Although studies of other polluted cities (those with local dominant forcings only) that employ "climatological" boundary conditions have been successful, this approach is not possible for the Paris region. Consequently, two new Chemistry Transport Models (CTM) were developed, named MOCAGE [Peuch et al., 1999] and CHIMERE [Vautard et al., 2001; Schmidt and Martin, 2003], from the regional to the global scale.
Determination of accurate boundary conditions requires the use of a realistic model at a larger scale than the studied area. The Paris area may appear as a "very urbanized island" in the middle of great rural areas. Thus, to have realistic simulations of pollutants in these rural areas, the large scale CTM needs realistic biogenic emissions. The ESQUIF project represented a good opportunity to more precisely study these biogenic emissions [C. Sarrat, 2002], [Derognat et al., 2003]. In the latter paper, a biogenic VOCs emission database was developed and used with the CHIMERE model (continental and regional scales). This database was validated during ESQUIF by comparison between model simulations and aircraft measurements of isoprene. Results showed that the difference was less than 10%. It was also shown that the continental contribution of biogenic VOCs to the Paris ozone plume may reach up to 35 ppb of ozone for temperatures larger than 35oC (for example during the IOP2).
Because emissions are some of the key inputs of CTMs, much work during ESQUIF focused on this aspect of air quality modeling. Since 1998, the Paris area has one of the best emissions inventories in France. This emissions inventory, provided by AIRPARIF, was used by all the model teams of the ESQUIF project. A critical comparison between surface and aircraft measurements and modeled concentrations of numerous VOCs is proposed by [Vautard et al., 2003].
| IOP | Date | Paris | Paris Area [150x150km] | |||||
| [O3] | [O3]max | Time | [O3] | [O3]max | Site | Time | ||
| ug/m3 | ug/m3 | (UTC) | ug/m3 | ug/m3 | (UTC) | |||
| 1 | 25 / 7 / 1998 | 61.4 | 115.0 | 15 | 64.6 | 146.0 | SW | 16 |
| 26 / 7 / 1998 | 61.4 | 135.0 | 15 | 64.7 | 148.0 | S | 14 | |
| 2 | 06 / 8 / 1998 | 45.3 | 147.0 | 15 | 52.8 | 157.0 | NE | 16 |
| 07 / 8 / 1998 | 41.0 | 149.0 | 13 | 54.9 | 260.0 | SW | 16 | |
| 08 / 8 / 1998 | 57.5 | 172.0 | 11 | 71.9 | 237.0 | W | 15 | |
| 09 / 8 / 1998 | 99.4 | 218.0 | 16 | 102.1 | 244.0 | SW | 16 | |
| 10 / 8 / 1998 | 71.5 | 226.0 | 12 | 78.9 | 225.0 | NE | 12 | |
| 11 / 8 / 1998 | 100.9 | 274.0 | 14 | 112.0 | 340.0 | NE | 15 | |
| 12 / 8 / 1998 | 69.6 | 134.0 | 2 | 75.8 | 129.0 | W | 2 | |
| 3 | 16 / 6 / 1999 | 54.2 | 150.0 | 13 | 65.7 | 211.0 | SW | 14 |
| 17 / 6 / 1999 | 56.9 | 133.0 | 12 | 73.0 | 176.0 | SE | 13 | |
| 18 / 6 / 1999 | 49.7 | 97.0 | 16 | 58.4 | 115.0 | SW | 15 | |
| 4 | 25 / 6 / 1999 | 78.4 | 145.0 | 13 | 86.7 | 167.0 | SW | 16 |
| 26 / 6 / 1999 | 61.0 | 117.0 | 12 | 66.1 | 138.0 | NE | 12 | |
| 5 | 01 / 7 / 1999 | 27.1 | 68.0 | 12 | 33.7 | 94.0 | SE | 10 |
| 02 / 7 / 1999 | 54.8 | 119.0 | 13 | 58.0 | 186.0 | NW | 14 | |
| 03 / 7 / 1999 | 43.9 | 81.0 | 10 | 47.5 | 101.0 | NE | 11 | |
| 6 | 16 / 7 / 1999 | 64.2 | 130.0 | 16 | 64.7 | 163.0 | E | 17 |
| 17 / 7 / 1999 | 74.3 | 166.0 | 12 | 78.8 | 266.0 | W | 16 | |
| 18 / 7 / 1999 | 95.3 | 179.0 | 13 | 88.3 | 191.0 | NW | 12 | |
| 19 / 7 / 1999 | 68.9 | 114.0 | 15 | 66.0 | 123.0 | SW | 14 | |
| 7 | 24 / 7 / 1999 | 5t.2 | 99.0 | 15 | 60.3 | 126.0 | SW | 14 |
| 25 / 7 / 1999 | 67.8 | 118.0 | 23 | 70.2 | 132.0 | W | 22 | |
| 26 / 7 / 1999 | 72.8 | 135.0 | 16 | 83.4 | 163.0 | SW | 15 | |
| 8 | 28 / 7 / 1999 | 76.1 | 140.0 | 13 | 93.4 | 185.0 | SW | 15 |
| 29 / 7 / 1999 | 78.5 | 165.0 | 15 | 94.9 | 228.0 | SW | 15 | |
| 30 / 7 / 1999 | 82.8 | 207.0 | 14 | 100.0 | 242.0 | W | 15 | |
| 31 / 7 / 1999 | 72.1 | 169.0 | 11 | 92.8 | 206.0 | NW | 13 | |
| 01 / 8 / 1999 | 66.3 | 156.0 | 15 | 88.4 | 189.0 | W | 15 | |
The study by [Vautard et al., 2003] examines the accuracy of the emissions inventory at the regional scale. Starting from a reference run (calculation of OH fields), a modified chemical mechanism of type VOC+OH allows for calculation of the concentration of individual VOCs. Qualitatively, and by comparison with aircraft measurements, the model reproduced well the spatial distributions of these emissions. However, it was shown that the model overestimates and underestimates various individual VOC species, whereas some other emitted species, such as NOx and CO, were accurately reproduced in the emissions inventory.
For ESQUIF, a Bayesian Monte Carlo uncertainty analysis was developped. Even if the measurement constraint from circular flights and ground based sites allows to significantly reduce the model uncertainty, it is still substantial, i.e. between 15 and 30% in ozone maxima, both for a reference and a 50% reduced emission scenario [Beekmann et al., 2003]. [Sillman et al., 2003] characterized the sensitivity of the Parisian plume to NOx and VOCs concentrations and showed that the Paris area is mainly VOC limited. Concerning emissions, and more generally on the whole set of CTM parameters, [Menut, 2003] proposed a classification of the meteorological and chemical processes that influence the final simulated concentrations of O3, Ox and NOx (IOP2 using an adjoint model).
Mainly produced by photolysis processes, ozone is particularly sensitive to the phenomena that attenuate solar UV radiation. This motivates two particular studies, the first one a direct comparison of measurements of J(NO2) within Paris with the TUV model, the second, a study of chemical partitioning within aerosols. On the basis of these analyses [Vautard and ESQUIF TEAM, 2001], the values of J(NO2) are only attenuated about 12% compared to the modelled reference values. Moreover, it was found that the majority of particles had diameters not exceeding 300 nm. Another study, using the CHIMERE model, allowed for implementation of a new parameterization of the attenuation of photolysis rates, one based on use of ECMWF cloud cover. According to a statistical regression, and after simulation of the entire summers of 1998 and 1999, it was shown that explicitly accounting for cloudiness considerably improved the simulations of surface ozone concentrations over Western Europe. This improvement is most significant in northern Europe, the area that is most cloudy.
In order to improve understanding of pollution processes, a major goal of this project is to improve the daily forecast of peak ozone abundances. Toward this goal, a method based on optimal interpolation was developed for regional scales [N. Blond, 2002]. This approach, which mathematically combines model simulations and measurements, allows for generation of maps of ozone concentrations that are as realistic as possible. This technique is now employed daily under the auspices of the PIONEER project [Pioneer] dedicated to daily forecast over Europe.
The ESQUIF project documented numerous episodes of photooxidant pollution in the Paris area. The measurements and results have improved our understanding of the processes that generate pollution within the Paris area, as well as the contributions of transport in and out of the Paris region to local and regional pollution. Many research topics were addressed, with specific results for the Paris area, but there were some results that can improve our understanding of other polluted cities.
From all the intensive observation periods, it was found that pollution events were observed even when stagnant conditions appeared only very recently. The maximum thickness of the ABL varies much during all the episodes, and it was observed that oxidant peaks occurred for low or high ABL height. Moreover, these episodes appeared even in the cases of not so marked temperature inversion.
Alone, activities in Paris and its suburbs can produce pollution peaks that are often moderate. The most significant peaks are the result of this local production, amplified by meteorological conditions that favor weak winds (and high temperatures) that confine air masses for several days to regions with strong emissions. This finding highlights the importance of transport of pollutants between countries in Western Europe, and, from an attribution point of view, the need for highly accurate chemical boundary conditions.
esquif_database.tar.gz (144 Mo) |
| Period | Data file |
| 25 to 28 July 1998 | Esqf_MF_Stat_poi1.lst |
| 5 to 12 August 1998 | Esqf_MF_Stat_poi2.lst |
| 16 June 1999 | Esqf_MF_Stat_poi3.lst |
| 25 June 1999 | Esqf_MF_Stat_poi4.lst |
| 2 July 1999 | Esqf_MF_Stat_poi5.lst |
| 16 to 18 July 1999 | Esqf_MF_Stat_poi6.lst |
| 24 to 25 July 1999 | Esqf_MF_Stat_poi7.lst |
| 28 to 31 July 1999 | Esqf_MF_Stat_poi8.lst |
| 7 October 1999 | Esqf_MF_Stat_poi9.lst |
| 26 to 27 January 2000 | Esqf_MF_Stat_poi10.lst |
| Pollutant | O3 | NO | NO2 | SO2 | CS2 | CH2O |
| threshold (ppb) | 1 | 3 | 1.5 | 0.3 | 6 | 1.7 |
| Pollutant | HNO2 | Toluene | Benzene | M-Xylene | P-Xylene | Naphtalene |
| threshold (ppb) | 0.7 | 3 | 2 | 1 | 1 | 0.2 |
| IOP | NHMC files | NOx files | PAN files |
| 6 | Mil6NMHC.txt | Mil6NOx.txt | Mil6PAN.txt |
| 7 | Mil7NMHC.txt | Mil7NOx.txt | Mil7PAN.txt |
| 8 | Mil8NMHC.txt | Mil8NOx.txt | Mil8PAN.txt |
| 9 | Mil9NMHC.txt | Mil9NOx.txt | Mil9PAN.txt |
| Date | Visible flux | Optical thickness | Boundary layer height |
| POI1 - 25/07/98 | FV_POI1_25071998 | OPTDEPTH_POI1_25071998 | HCLA_POI1_25071998 |
| POI1 - 26/07/98 | FV_POI1_26071998 | OPTDEPTH_POI1_26071998 | HCLA_POI1_26071998 |
| POI2 - 07/08/98 | |||
| POI2 - 08/08/98 | FV_POI2_08081998 | OPTDEPTH_POI2_08081998 | HCLA_POI2_08081998 |
| POI2 - 09/08/98 | FV_POI2_09081998 | OPTDEPTH_POI2_09081998 | HCLA_POI2_09081998 |
| POI3 - 16/06/99 | FV_POI3_16061999 | OPTDEPTH_POI3_16061999 | HCLA_POI3_16061999 |
| POI3 - 17/06/99 | HCLA_POI3_17061999 | ||
| POI4 - 25/06/99 | FV_POI4_25061999 | OPTDEPTH_POI4_25061999 | HCLA_POI4_25061999 |
| POI4 - 26/06/99 | FV_POI4_26061999 | ||
| POI5 - 01/07/99 | FV_POI5_01071999 | ||
| POI5 - 02/07/99 | OPTDEPTH_POI5_02071999 | HCLA_POI5_02071999 | |
| POI6 - 16/07/99 | FV_POI6_16071999 | OPTDEPTH_POI6_16071999 | HCLA_POI6_16071999 |
| POI6 - 17/07/99 | FV_POI6_17071999 | OPTDEPTH_POI6_17071999 | HCLA_POI6_17071999 |
| POI6 - 18/07/99 | FV_POI6_18071999 | OPTDEPTH_POI6_18071999 | HCLA_POI6_18071999 |
| Date | PR2 - Time | PR2 - Height | PR2 - Profiles |
| POI1 - 25/07/98 | T_poi1_25071998 | X_poi1_25071998 | PR2_poi1_25071998 |
| POI1 - 26/07/98 | T_poi1_26071998 | X_poi1_26071998 | PR2_poi1_26071998 |
| POI2 - 08/08/98 | T_poi2_08081998 | X_poi2_08081998 | PR2_poi2_08081998 |
| POI2 - 09/08/98 | T_poi2_09081998 | X_poi2_09081998 | PR2_poi2_09081998 |
| POI3 - 16/06/99 | T_poi3_16061999 | X_poi3_16061999 | PR2_poi3_16061999 |
| POI3 - 17/06/99 | T_poi3_17061999 | X_poi3_17061999 | PR2_poi3_17061999 |
| POI4 - 25/06/99 | T_poi4_25061999 | X_poi4_25061999 | PR2_poi4_25061999 |
| POI5 - 02/07/99 | T_poi5_02071999 | X_poi5_02071999 | PR2_poi5_02071999 |
| POI6 - 16/07/99 | T_poi6_16071999 | X_poi6_16071999 | PR2_poi6_16071999 |
| POI6 - 17/07/99 | T_poi6_17071999 | X_poi6_17071999 | PR2_poi6_17071999 |
| POI6 - 18/07/99 | T_poi6_18071999 | X_poi6_18071999 | PR2_poi6_18071999 |
| POI | Date | Heure (T.U) | Raw files PTU | Raw files wind | Saved points | Raw files after analysis | Saved points after analysis |
| 1 | 250798 | 23h15 | cra425.raw | crv425.raw | RST_raw_250798_2315 | ||
| 1 | 260798 | 06h00 | cra426.raw | crv426.raw | RST_raw_260798_0600 | ||
| 1 | 260798 | 09h00 | cra427.raw | crv427.raw | RST_raw_260798_0900 | ||
| 1 | 260798 | 11h15 | cra428.raw | crv428.raw | RST_raw_260798_1115 | ||
| 1 | 260798 | 15h00 | cra429.raw | crv429.raw | RST_raw_260798_1500 | ||
| 1 | 260798 | 18h00 | cra430.raw | crv430.raw | RST_raw_260798_1800 | ||
| 1 | 260798 | 23h15 | cra431.raw | crv431.raw | RST_raw_260798_2315 | ||
| 2 | 060898 | 23h16 | CRA453.RAW | CRV453.RAW | 98_64535.RET | RST_raw_060898_2316 | RST_ret_060898_2316 |
| 2 | 070898 | 05h32 | CRA454.RAW | CRV454.RAW | 98_64536.RET | RST_raw_070898_0532 | RST_ret_070898_0532 |
| 2 | 070898 | 08h27 | CRA455.RAW | CRV455.RAW | 98_64537.RET | RST_raw_070898_0827 | RST_ret_070898_0827 |
| 2 | 070898 | 11h19 | CRA456.RAW | CRV456.RAW | 98_64538.RET | RST_raw_070898_1119 | RST_ret_070898_1119 |
| 2 | 070898 | 14h30 | CRA457.RAW | CRV457.RAW | 98_64539.RET | RST_raw_070898_1430 | RST_ret_070898_1430 |
| 2 | 070898 | 17h27 | CRA458.RAW | CRV458.RAW | 98_64540.RET | RST_raw_070898_1727 | RST_ret_070898_1727 |
| 2 | 070898 | 23h18 | CRA459.RAW | CRV459.RAW | 98_64541.RET | RST_raw_070898_2318 | RST_ret_070898_2318 |
| 2 | 080898 | 05h28 | CRA460.RAW | CRV460.RAW | 98_64542.RET | RST_raw_080898_0528 | RST_ret_080898_0528 |
| 2 | 080898 | 08h30 | CRA461.RAW | CRV461.RAW | 98_64543.RET | RST_raw_080898_0830 | RST_ret_080898_0830 |
| 2 | 080898 | 11h18 | CRA462.RAW | CRV462.RAW | 98_64544.RET | RST_raw_080898_1118 | RST_ret_080898_1118 |
| 2 | 080898 | 14h28 | CRA463.RAW | CRV463.RAW | 98_64545.RET | RST_raw_080898_1428 | RST_ret_080898_1428 |
| 2 | 080898 | 17h27 | CRA464.RAW | CRV464.RAW | 98_64546.RET | RST_raw_080898_1727 | RST_ret_080898_1727 |
| 2 | 080898 | 23h17 | CRA465.RAW | CRV465.RAW | 98_64547.RET | RST_raw_080898_2317 | RST_ret_080898_2317 |
| 2 | 090898 | 05h34 | CRA466.RAW | CRV466.RAW | 98_64548.RET | RST_raw_090898_0534 | RST_ret_090898_0534 |
| 2 | 090898 | 08h28 | CRA467.RAW | CRV467.RAW | 98_64549.RET | RST_raw_090898_0828 | RST_ret_090898_0828 |
| 2 | 090898 | 11h16 | CRA468.RAW | CRV468.RAW | 98_64550.RET | RST_raw_090898_1116 | RST_ret_090898_1116 |
| 2 | 090898 | 14h25 | CRA469.RAW | CRV469.RAW | 98_64551.RET | RST_raw_090898_1425 | RST_ret_090898_1425 |
| 2 | 090898 | 17h26 | CRA470.RAW | CRV470.RAW | 98_64552.RET | RST_raw_090898_1726 | RST_ret_090898_1726 |
| 2 | 090898 | 23h16 | CRA471.RAW | CRV471.RAW | 98_64553.RET | RST_raw_090898_2316 | RST_ret_090898_2316 |
| 3 | 150699 | 23h15 | CRA340.RAW | CRV340.RAW | 99_65190.RET | RST_raw_150699_2315 | RST_ret_150699_2315 |
| 3 | 160699 | 11h29 | CRA341.RAW | CRV341.RAW | 99_65191.RET | RST_raw_160699_1129 | RST_ret_160699_1129 |
| 3 | 160699 | 23h18 | CRA342.RAW | CRV342.RAW | 99_65192.RET | RST_raw_160699_2318 | RST_ret_160699_2318 |
| 3 | 170699 | 11h50 | CRA343.RAW | CRV343.RAW | 99_65193.RET | RST_raw_170699_1150 | RST_ret_170699_1150 |
| 3 | 170699 | 23h14 | CRA344.RAW | CRV344.RAW | 99_65194.RET | RST_raw_170699_2314 | RST_ret_170699_2314 |
| 4 | 240699 | 23h16 | CRA358.RAW | CRV358.RAW | 99_65208.RET | RST_raw_240699_2316 | RST_ret_240699_2316 |
| 4 | 250699 | 08h58 | CRA359.RAW | CRV359.RAW | 99_65209.RET | RST_raw_250699_0858 | RST_ret_250699_0858 |
| 4 | 250699 | 11h14 | CRA360.RAW | CRV360.RAW | 99_65210.RET | RST_raw_250699_1114 | RST_ret_250699_1114 |
| 4 | 250699 | 15h01 | CRA361.RAW | CRV361.RAW | 99_65211.RET | RST_raw_250699_1501 | RST_ret_250699_1501 |
| 4 | 250699 | 23h19 | CRA362.RAW | CRV362.RAW | 99_65212.RET | RST_raw_250699_2319 | RST_ret_250699_2319 |
| 4 | 260699 | 11h19 | CRA363.RAW | CRV363.RAW | 99_65213.RET | RST_raw_260699_1119 | RST_ret_260699_1119 |
| 5 | 300699 | 23h12 | CRA372.RAW | CRV372.RAW | 99_65222.RET | RST_raw_300699_2312 | RST_ret_300699_2312 |
| 5 | 010799 | 11h33 | CRA373.RAW | CRV373.RAW | 99_65223.RET | RST_raw_010799_1133 | RST_ret_010799_1133 |
| 5 | 010799 | 23h32 | CRA374.RAW | CRV374.RAW | 99_65224.RET | RST_raw_010799_2332 | RST_ret_010799_2332 |
| 5 | 020799 | 08h59 | CRA375.RAW | CRV375.RAW | 99_65225.RET | RST_raw_020799_0859 | RST_ret_020799_0859 |
| 5 | 020799 | 11h17 | CRA376.RAW | CRV376.RAW | 99_65226.RET | RST_raw_020799_1117 | RST_ret_020799_1117 |
| 5 | 020799 | 15h05 | CRA377.RAW | CRV377.RAW | 99_65227.RET | RST_raw_020799_1505 | RST_ret_020799_1505 |
| 6 | 150799 | 23h14 | CRA404.RAW | CRV404.RAW | 99_65254.RET | RST_raw_150799_2314 | RST_ret_150799_2314 |
| 6 | 160799 | 11h24 | CRA405.RAW | CRV405.RAW | 99_65255.RET | RST_raw_160799_1124 | RST_ret_160799_1124 |
| 6 | 160799 | 23h16 | CRA406.RAW | CRV406.RAW | 99_65256.RET | RST_raw_160799_2316 | RST_ret_160799_2316 |
| 6 | 170799 | 11h13 | CRA407.RAW | CRV407.RAW | 99_65257.RET | RST_raw_170799_1113 | RST_ret_170799_1113 |
| 6 | 170799 | 23h15 | CRA408.RAW | CRV408.RAW | 99_65258.RET | RST_raw_170799_2315 | RST_ret_170799_2315 |
| 6 | 180799 | 11h16 | CRA409.RAW | CRV409.RAW | 99_65259.RET | RST_raw_180799_1116 | RST_ret_180799_1116 |
| 6 | 180799 | 23h17 | CRA410.RAW | CRV410.RAW | 99_65260.RET | RST_raw_180799_2317 | RST_ret_180799_2317 |
| 7 | 230799 | 23h19 | CRA420.RAW | CRV420.RAW | 99_65270.RET | RST_raw_230799_2319 | RST_ret_230799_2319 |
| 7 | 240799 | 11h12 | CRA421.RAW | CRV421.RAW | 99_65271.RET | RST_raw_240799_1112 | RST_ret_240799_1112 |
| 7 | 240799 | 23h19 | CRA422.RAW | CRV422.RAW | 99_65272.RET | RST_raw_240799_2319 | RST_ret_240799_2319 |
| 7 | 250799 | 11h18 | CRA423.RAW | CRV423.RAW | 99_65273.RET | RST_raw_250799_1118 | RST_ret_250799_1118 |
| 7 | 250799 | 23h13 | CRA424.RAW | CRV424.RAW | 99_65274.RET | RST_raw_250799_2313 | RST_ret_250799_2313 |
| 8 | 270799 | 23h15 | CRA428.RAW | CRV428.RAW | 99_65278.RET | RST_raw_270799_2315 | RST_ret_270799_2315 |
| 8 | 280799 | 23h17 | CRA430.RAW | CRV430.RAW | 99_65280.RET | RST_raw_280799_2317 | RST_ret_280799_2317 |
| 8 | 290799 | 11h26 | CRA431.RAW | CRV431.RAW | 99_65281.RET | RST_raw_290799_1126 | RST_ret_290799_1126 |
| 8 | 290799 | 23h15 | CRA432.RAW | CRV432.RAW | 99_65282.RET | RST_raw_290799_2315 | RST_ret_290799_2315 |
| 8 | 300799 | 11h17 | CRA433.RAW | CRV433.RAW | 99_65283.RET | RST_raw_300799_1117 | RST_ret_300799_1117 |
| 8 | 300799 | 23h16 | CRA434.RAW | CRV434.RAW | 99_65284.RET | RST_raw_300799_2316 | RST_ret_300799_2316 |
| 8 | 310799 | 11h16 | CRA435.RAW | CRV435.RAW | 99_65285.RET | RST_raw_310799_1116 | RST_ret_310799_1116 |
| 8 | 310799 | 23h12 | 99_65286.RET | RST_ret_310799_2312 | |||
| 9 | 061099 | 23h14 | CRA597.RAW | CRV597.RAW | 99_65447.RET | RST_raw_061099_2314 | RST_ret_061099_2314 |
| 9 | 071099 | 06h08 | CRA598.RAW | CRV598.RAW | 99_65448.RET | RST_raw_071099_0608 | RST_ret_071099_0608 |
| 9 | 071099 | 09h01 | CRA599.RAW | CRV599.RAW | 99_65449.RET | RST_raw_071099_0901 | RST_ret_071099_0901 |
| 9 | 071099 | 11h23 | CRA600.RAW | CRV600.RAW | 99_65450.RET | RST_raw_071099_1123 | RST_ret_071099_1123 |
| 9 | 071099 | 15h12 | CRA601.RAW | CRV601.RAW | 99_65451.RET | RST_raw_071099_1512 | RST_ret_071099_1512 |
| 9 | 071099 | 23h16 | CRA602.RAW | CRV602.RAW | 99_65452.RET | RST_raw_071099_2316 | RST_ret_071099_2316 |
| 9 | 081099 | 06h35 | CRA603.RAW | CRV603.RAW | 99_65453.RET | RST_raw_081099_0635 | RST_ret_081099_0635 |
| 9 | 081099 | 09h24 | CRA604.RAW | CRV604.RAW | 99_65454.RET | RST_raw_081099_0924 | RST_ret_081099_0924 |
| 9 | 081099 | 11h22 | CRA605.RAW | CRV605.RAW | 99_65455.RET | RST_raw_081099_1122 | RST_ret_081099_1122 |
| 9 | 081099 | 23h18 | CRA606.RAW | CRV606.RAW | 99_65456.RET | RST_raw_081099_2318 | RST_ret_081099_2318 |
| 10 | 250100 | 23h19 | CRA053.RAW | 00_65717.RET | RST_raw_250100_2319 | RST_ret_250100_2319 | |
| 10 | 260100 | 06h10 | CRA054.RAW | CRV054.RAW | 00_65718.RET | RST_raw_260100_0610 | RST_ret_260100_0610 |
| 10 | 260100 | 09h02 | CRA055.RAW | CRV055.RAW | 00_65719.RET | RST_raw_260100_0902 | RST_ret_260100_0902 |
| 10 | 260100 | 11h41 | CRA056.RAW | CRV056.RAW | 00_65720.RET | RST_raw_260100_1141 | RST_ret_260100_1141 |
| 10 | 260100 | 15h00 | CRA057.RAW | CRV057.RAW | 00_65721.RET | RST_raw_260100_1500 | RST_ret_260100_1500 |
| 10 | 260100 | 23h27 | CRA058.RAW | CRV058.RAW | 00_65722.RET | RST_raw_260100_2327 | RST_ret_260100_2327 |
| 10 | 270100 | 06h32 | CRA059.RAW | CRV059.RAW | 00_65723.RET | RST_raw_270100_0632 | RST_ret_270100_0632 |
| 10 | 270100 | 09h12 | CRA060.RAW | CRV060.RAW | 00_65724.RET | RST_raw_270100_0912 | RST_ret_270100_0912 |
| 10 | 270100 | 11h36 | CRA061.RAW | CRV061.RAW | 00_65725.RET | RST_raw_270100_1136 | RST_ret_270100_1136 |
| 10 | 270100 | 15h04 | CRA062.RAW | CRV062.RAW | 00_65726.RET | RST_raw_270100_1504 | RST_ret_270100_1504 |
| 10 | 270100 | 23h15 | CRA063.RAW | CRV063.RAW | 00_65727.RET | RST_raw_270100_2315 | RST_ret_270100_2315 |
| 10 | 280100 | 11h27 | CRA064.RAW | CRV064.RAW | 00_65728.RET | RST_raw_280100_1127 | RST_ret_280100_1127 |
| Flight no |
Type | Date | start/end time | freq. 1S | freq. 30S | PAN |
| 38 | [Chemical regime 1] | 17/07/99 | 10:55/14:25 | V38-1S2.TXT | V38_30s.txt | V38PAN.txt |
| 39 | [Chemical regime 2] | 17/07/99 | 15:05/17:53 | V39-1S2.TXT | V39_30s.txt | V39PAN.txt |
| 40 | [Plume 1] | 29/07/99 | 11:05/13:37 | V40-S2.TXT | V40_30s.txt | V40PAN.txt |
| 41 | [Plume 2] | 29/07/99 | 14:51/17:08 | V41-1S2.TXT | V41_30s.txt | V41PAN.txt |
| 42 | [Chemical regime 3] | 30/07/99 | 11:57/14:48 | V42-1S2.TXT | V42_30s.txt | V42PAN.txt |
| POI | Flight # | Date | Summary | Data |
| 1 | 0298 | 22 Juillet 1998 | az0298.htm | ~ |
| 1 | 0598 | 25 Juillet 1998 | az0598.htm | az9805_1 |
| 1 | 0698 | 26 Juillet 1998 | az0698.htm | az9806_1 |
| 1 | 0798 | 26 Juillet 1998 | az0798.htm | az9807_1 |
| 1 | 0898 | 26 Juillet 1998 | az0898.htm | az9808_1 |
| 2 | 0998 | 7 Aout 1998 | az0998.htm | az9809_1 |
| 2 | 1098 | 7 Aout 1998 | az1098.htm | az9810_1 |
| 2 | 1198 | 8 Aout 1998 | az1198.htm | az9811_1 |
| 2 | 1298 | 8 Aout 1998 | az1298.htm | az9812_1 |
| 2 | 1398 | 8 Aout 1998 | az1398.htm | az9813_1 |
| 2 | 1498 | 9 Aout 1998 | az1498.htm | az9814_1 |
| 2 | 1598 | 9 Aout 1998 | az1598.htm | az9815_1 |
| POI | Flight # | date | Begin | End | Take-off | Landing | Data |
| 4 | 17 | 25 juin | 11h24m19s | 14h15m21s | 11h40m38s | 14h15m21s | az9917_1 |
| 5 | 18 | 02 juil. | 06h53m21s | 09h39m00s | 07h0m908s | 09h08m09s | az9918_1 |
| 5 | 19 | 02 juil. | 11h58m48s | 15h07m19s | 12h1m500s | 15h07m20s | az9919_1 |
| 6 | 23 | 16 juil. | 11h42m54s | 14h29m03s | 12h0m023s | 14h29m03s | az9923_1 |
| 6 | 24 | 17 juil. | 06h58m26s | 10h13m00s | 07h1m307s | 10h11m02s | az9924_1 |
| 6 | 25 | 17 juil. | 11h58m33s | 15h18m54s | 12h0m850s | 15h15m19s | az9925_1 |
| 8 | 27 | 29 juil. | 06h22m15s | 08h27m39s | 06h3m543s | 08h27m39s | az9927_1 |
| 8 | 28 | 29 juil. | 12h02m40s | 13h39m00s | 12h1m939s | 13h32m47s | az9928_1 |
| 9 | 34 | 07oct. | 08h48m21s | 10h28m39s | 09h0m300s | 10h25m30s | az9934_1 |
| Flight (Date) | morning flight | afternoon flight | remarks (details below) |
| F990625A | 08:12 - 10:22 | ||
| F990625B | 12:21 - 16:21 | ||
| F990702A | 07:32 - 09:54 | no C4 | |
| F990702B | 12:22 - 16:34 | no C4 | |
| F990716A | 11:35 - 15:36 | no NOxTOy after 3 h | |
| F990717A | 07:54 - 1005 | ||
| F990717B | 14:16 - 18:24 | late, but, "best" O3-plume found | |
| F990718A | 08:00 - 10:21 | remarkable reservoir layer | |
| F990718B | 12:16 - 16:15 |
| Flight | Files MIN | Files GCD | Files 10S |
| F990625A | F990625A.MIN | F990625A.GCD | F990625A.10S |
| F990625B | F990625B.MIN | F990625B.GCD | F990625B.10S |
| F990702A | F990702A.MIN | F990702A.GCD | F990702A.10S |
| F990702B | F990702B.MIN | F990702B.GCD | F990702B.10S |
| F990716A | F990716A.MIN | F990716A.GCD | F990716A.10S |
| F990717A | F990717A.MIN | F990717A.GCD | F990717A.10S |
| F990717B | F990717B.MIN | F990717B.GCD | F990717B.10S |
| F990718A | F990718A.MIN | F990718A.GCD | F990718A.10S |
| F990718B | F990718B.MIN | F990718B.GCD | F990718B.10S |
| Flight | Date | Start | End | Flight notes | File |
| 9835 | 7 August 1998 | 06h09 | 07h11 | me3598.htm | me9835_1.V2.asc |
| 9836 | 7 August 1998 | 12h24 | 15h40 | me3698.htm | me9836_1.V2.asc |
| 9837 | 8 August 1998 | 04h53 | 08h32 | me3798.htm | me9837_1.V2.asc |
| 9838 | 8 August 1998 | 12h32 | 14h48 | me3898.htm | me9838_1.V2.asc |
| 9839 | 9 August 1998 | 04h51 | 08h26 | me3998.htm | me9839_1.V2.asc |
| 9840 | 9 August 1998 | 12h54 | 15h13 | me4098.htm | me9840_1.V2.asc |
| Flight | Date | Header | File |
| 9913 | 25 Juin 1999 Afternoon (POI4) | me9913_1.f99.v2.txt | me9913_1.f99.v2.asc |
| 9914 | 02 July 1999 Afternoon (POI5) | me9914_1.f99.v2.txt | me9914_1.f99.v2.asc |
| 9915 | 17 July 1999 Afternoon (POI6) | me9915_1.f99.v2.txt | me9915_1.f99.v2.asc |
| 9916 | 18 July 1999 Morning (POI6) | me9916_1.f99.v2.txt | me9916_1.f99.v2.asc |
| 9917 | 25 July 1999 Morning (POI7) | me9917_1.f99.v2.txt | me9917_1.f99.v2.asc |
| 9918 | 25 July 1999 Afternoon (POI7) | me9918_1.f99.v2.txt | me9918_1.f99.v2.asc |
| 9919 | 29 July 1999 Intercomparison (POI8) | me9919_1.f99.v2.txt | me9919_1.f99.v2.asc |
| 9920 | 30 July 1999 Morning (POI8) | me9920_1.f99.txt | me9920_1.f99.asc |
| 9921 | 30 July 1999 Afternoon (POI8) | me9921_1.f99.txt | me9921_1.f99.asc |